Wednesday, August 20, 2008

"Unconventional" Gas Plays

More information from the online "World Oil Magazine" on the "Shale Gas" plays in the United States. (source)

Peter



SPECIAL FOCUS: NORTH AMERICAN OUTLOOK- UNCONVENTIONAL RESOURCES
Unconventional plays grow in number after Barnett Shale blazed the way
The Haynesville and Marcellus are becoming exciting new gas plays, while activity in the Woodford and Fayetteville continues.
Katrina Boughal , Technical Editor
Unconventional gas plays in the US have been booming since technological advances increased production in the now-famous Barnett Shale. Horizontal drilling and fracture stimulation in the shale source rock, as opposed to the sandstone/limestone/dolomite reservoir rock, have proved to be successful not only in gas plays like the Barnett, Fayetteville and Woodford, but also in the Bakken-a primarily oil-rich formation.

Resources that were previously thought to be unrecoverable are now being reassessed and, in some cases, rediscovered. Many shale plays have been producing a small amount of gas for years (the Indiana and Kentucky New Albany Shale since the late 1880s), but with the Barnett example, they are becoming more successful. Hot plays in the industry include the Louisiana/Texas Haynesville and Bossier Shales, and the Marcellus of Pennsylvania/Appalachia. The Williston Basin Bakken Formation has also gained popularity after a recent reassessment by the USGS.

HAYNESVILLE
The fairly recent Haynesville gas play, having garnered attention over the past few months, is an Upper Jurassic formation overlain by the Cotton Valley Group, and lies over the Smackover Formation. The Haynesville is an ultra-low permeability shale, and is focused in northwest Louisiana and East Texas, particularly in Caddo, Bossier and DeSoto Parishes, but also to a lesser extent in Red River and Sabine Parishes, and Harrison and Panola Counties, Fig. 1. The Haynesville Shale underlies the Bossier Shale (part of the Cotton Valley Group), and they are sometimes referred to as the same unit or related units. 2 Deeper than most shale gas plays, the Haynesville is located at depths ranging between 11,000 and 13,000 ft. 3

Fig. 1 . Map of the Haynesville Shale play (shaded). 1
Chesapeake is a large participant in the Haynesville play, holding about 550,000 acres as of late June 2008, with plans to acquire more acreage. Chesapeake entered a joint venture with Plains Exploration and Production, and the companies plan to drill about 600 wells in the Haynesville in the next three years. Chesapeake is estimating a mid-point estimated ultimate reserve of 6.5 Bcf, and their initial horizontal production rates are encouraging for the play.
“The initial production rates on the eight horizontal wells we have completed have ranged from 5 to 15 MMcfd on restricted chokes at flowing casing pressures of up to 6,500 psi,” said Chesapeake CEO Aubrey K. McClendon. 4

Petrohawk is also an active participant with about 275,000 acres, and completed their first horizontal well in the Haynesville in late June 2008. The Elm Grove Plantation #63, drilled in Bossier Parish, encountered about 212 ft of Haynesville Shale, and produced at a rate of 16.8 MMcfd. Completion of Elm Grove Plantation #63 included 11 stages of fracture stimulation. Petrohawk is drilling three horizontal wells, and expects to be operating six rigs in the Haynesville by mid-September 2008. 5

Companies are scrambling to lease plots in the Haynesville, with Forest Oil announcing in late June 2008 a net holding of 90,000 acres in the area. 6 GMX Resources added 7,300 net acres in early July, bringing its total acreage to 27,500. 7 EnCana has about 325,000 acres in the Haynesville, and completed a horizontal well in February with an initial production rate of 8 MMcfd. 8

FAYETTEVILLE
A few years ago the Fayetteville Shale experienced an upswing in interest somewhat akin to what the Haynesville is experiencing now. The Fayetteville of Arkansas is a Mississippian formation on the eastern end of the Arkoma Basin, with thicknesses varying between 50 and 300 ft and drilled at depths ranging from 2,000 to 6,000 ft. Thickness in the Fayetteville differs from east to west, at about 50 to 75 ft thick in western Arkansas to about 300 ft at the eastern edge of the Arkoma Basin. The formation is productive from its middle to base because the lower section is rich in organic material, with chert and siliceous interbedding. 9 The unit is thermally mature, and is differentiated from surrounding units by high radioactivity and resistivity signatures. 10

The Fayetteville is found in multiple eastern and central Arkansas counties, including Cleburne, Conway, Faulkner, Franklin, Jackson, St. Francis, Pope, Prairie, Van Buren, White and Woodruff Counties. The Fayetteville is about the same age and is seen as a geologic equivalent to the Barnett Shale near Fort Worth.

The Fayetteville followed the Barnett in production technology. As with other shale gas plays, the Fayetteville was previously known to be a gas-bearing formation, but only produced when horizontal drilling and fracture stimulation were introduced. 8 Some 460 of the over 500 producing wells in the Fayetteville are horizontal, and total production from the shale has reached, and likely exceeded, 52 Bcf. 11

Rig counts in the Arkansas Arkoma Basin have increased dramatically in the past two years. In August 2006, the rig count hovered at slightly over 20. In early July 2008, the count was at 59 operating rigs, with most located in Van Buren, White and Conway Counties. Southwestern Energy was operating 18 of the 59 rigs (about 31%) in the Arkansas Arkoma Basin during the first week of July 2008. 12 Southwestern, one of the most dominant players in the region, owns about 851,100 acres in the Fayetteville area, and has completed 557 wells in the play as of March 2008, of which about 88% were horizontal. During the company’s first quarter 2008, estimated 2007 production from the Fayetteville was 53.5 Bcf. 13

Chesapeake holds the largest land area in the play with 1.1 million acres, and in March 2008, had a net production of 130 MMcfd from the Fayetteville. Chesapeake had 12 rigs operating in March 2008, and plans to escalate drilling activity to 25 rigs in the play by early 2009. 14

MARCELLUS
In 2002, the USGS released an assessment of the undiscovered oil and gas in the Appalachian Basin Province. The Marcellus Shale was characterized as an individual assessment unit in the Appalachian Basin region that contained gas resources of about 1.9 Tcf. 15

The Marcellus had been fairly quiet until recently, when in late 2007 Range Resources announced horizontal well test rates from 1.4 MMcfd to 4.7 MMcfd. Shortly after, in January 2008, Pennsylvania State University and the University of New York at Fredonia released a report estimating recoverable reserves at 50 Tcf. Since then, The New York Times and USA Today have run stories on the Marcellus and the formation’s producing potential.

The Marcellus Shale is part of a large suite of rocks known as the Devonian shales, and stretches NE-SW about 600 mi across several Appalachian states, including New York, Pennsylvania and West Virginia, Fig. 2. 16 The naturally fractured, dry gas-producing Marcellus covers an area of about 54,000 square mi, 17 and ranges in thickness from 50 to 200 ft. Like the Fayetteville, the Marcellus thins from east to west, with 200-ft sections in northeastern Pennsylvania and 50-ft sections in northern West Virginia, Ohio, Pennsylvania and western New York. The formation depth ranges from 5,000 to 8,000 ft below sea level. 18

Fig. 2 . Map of the Marcellus and Devonian Shales. 16
The organic richness of the Marcellus, however, decreases generally from north in New York to south in West Virginia. The thermal maturity of the shale is an estimated 1.5 to 3% vitrinite reflectance (Ro). 18

As of April 2008, Range Resources held about 1.15 million acres of the Marcellus play, and had drilled 10 successful horizontal wells with initial production rates ranging from 2.6 to 5.8 MMcfd. 19 Other players in the Marcellus include Atlas Energy Resources and Chesapeake (largest lease holder with 1.2 million acres). Atlas, whose drilling plan is focused primarily in southwestern Pennsylvania, announced in February that it had 21 producing vertical wells, with 6 more due to be completed and producing shortly. 20

Marcellus players face the problem of minimal public information on the area, and have to resort to academic papers and regional geologic information due to the lack of log data. Oilfield services and equipment in the area are also somewhat scarce, with only four or six Appalachian rigs capable of drilling horizontal wells. 16

WOODFORD
Activity in the Woodford Shale began in 2003-2004 as a vertical play, but quickly transitioned to horizontal wells after the Barnett became horizontally driven. 21
The Woodford Shale is located in Oklahoma on the western end of the Arkoma Basin, and ranges in age from Middle Devonian to Early Mississippian. The stratigraphic equivalent to the Bakken and Antrim Shales, the Woodford shows a wide range of thermal maturities from 0.7 to 4.89% Ro?. Although known to be a gas-producing formation, the Woodford may have the potential to produce oil as well, 22 and the silica-rich shale has provided a good environment for fracturing due to its brittle nature. 21

The Woodford has seen many players in the area including Newfield Exploration, Devon, Chesapeake and XTO Energy. Newfield has about 165,000 net acres in the Woodford, is looking to drill about 100 horizontal wells this year and had a gross production of 165 MMcfd as of February 2008.23 Drilling depths for Newfield have ranged from 6,000 to 13,000 ft, with lateral lengths to about 5,000 ft. 21 For a more in-depth discussion on the characteristics and production potential of the Woodford Shale, please see page 83.

BARNETT
No unconventional play article would be complete without a mention of the Barnett. The very well-known Barnett Shale is the gas play that introduced horizontal drilling and fracture stimulation techniques to the unconventional shale gas field, allowing other plays’ production potential to be realized. Indeed, every time a new shale gas play is discovered, it is compared to the Barnett, or is called the “next Barnett” or a “baby Barnett.”

The Mississippian Barnett in the Fort Worth Basin of Texas is about 6,500 to 8,000 ft deep, and thickens toward the northeast-from about 30 to 50 ft thick in the south to about 1,000 ft thick in the northeast. 24

At the end of 2007, the total number of Barnett producing wells over time was at about 8,960, with cumulative production of 3.69 Tcf and 11.6 million bbl of oil. The rate of production from 8,435 active Barnett wells in December 2007 was 3.524 Bcfd plus 7,477 bpd. From 2003 to 2007, horizontal wells have become the dominant well orientation. In 2003, about 21% of wells completed in the Barnett were horizontal; in 2007, about 94% were horizontal. 25

The Barnett continues as the giant that it has become in the past five years. The players list in the Barnett is exhaustive, with Devon, Chesapeake, XTO, Encana, EOG and others. Devon has drilled more than 1,300 wells in the Barnett since 2002, and produces nearly 600 MMcfd. 26

BAKKEN
The April 2008 USGS assessment of the Bakken Formation in the Williston Basin has caused a flurry of activity in the area, particularly because of the undiscovered, technically recoverable oil resource estimation-between 3.0 and 4.3 billion bbl. The large increase in the Bakken’s recoverable resources (formerly estimated by the USGS at 151 million bbl in 1995) is due to the same factor that has lead to expanding shale gas plays: advances in horizontal drilling and hydraulic fracturing.

The Upper Devonian-Early Mississippian Bakken is a continuous, 200,000-sq mi formation composed of sandstone, siltstone and dolomite bounded by two shale layers. Average porosity in the Bakken is between 8% and 12%, and permeability ranges from 0.05 mD to 0.5 mD. The Bakken is about 2-mi deep, and has a net thickness of about 6 ft to 15 ft. Key players in the region include EOG Resources, Whiting Petroleum, Brigham Exploration, Hess, Newfield Exploration, XTO and Marathon. 27 For a more comprehensive view on the Bakken assessment, please see World Oil June 2008, page 83.

OTHER PLAYS
There are a multitude of unconventional shale plays being assessed, and the following are a few from various parts of the US.
Utica. Located in New York, northern Pennsylvania, Quebec and Ontario, the Utica Shale is an Upper Ordovician reservoir with typical low permeability, high organic content and varying thickness-the formation ranges from 150 to 1,000 ft across New York. The Utica’s close proximity to the Marcellus makes it interesting, but recently drilled Utica wells have “not responded well to the normal shale fracturing practices.” 28 Forest Oil has acquired 269,000 net acres of the Quebec Utica, and in April 2008, reported 1 MMcfd production rates from two 4,800-ft vertical wells. 29

Chattanooga.

This Devonian shale formation extends across a large part of the US, although the gas play is centered in southern Kentucky, eastern Tennessee and northern Alabama, Fig. 3. Sources cite the Chattanooga as being an equivalent to both the Marcellus and the Woodford Shales, all of which are Devonian formations. 30,31


Fig. 3 . Map of the Chattanooga Shale play (shaded). 30
The USGS reported in 2007 on the petroleum system of the Black Warrior Basin in Alabama and Mississippi that encompasses part of the Chattanooga Shale. The USGS report focused on the carbonates and sandstones, and discussed the Floyd and Chattanooga Shales as source rocks alone-no unconventional shale gas assessment was released. The Chattanooga is a Devonian-age shale that is separated from the Mississippian-age Floyd Shale by a thin layer of chert and limestone, and they are often referred in relation to each other. The Alabama Chattanooga play lies in the eastern Black Warrior Basin, and is a thin unit with a Total Organic Carbon (TOC) weight percent range of 2.4-12.7. 32 The Tennessee Chattanooga play is relatively shallow compared to other gas plays with depths ranging from 1,500 to 2,000 ft. 33

In 2007, CNX Gas Corp. drilled a horizontal well in Tennessee with an initial production rate of 3.9 MMcfd. 34 Atlas Energy Resources announced in June 2008 the successful drilling of four horizontal wells in the formation. 35

Floyd. In close contact with the Chattanooga Shale, the Floyd play is situated in the Black Warrior Basin of Mississippi and Alabama. The formation is primarily shale, but also contains clay, sandstone and limestone beds, with chert and large siderite modules. 32 Found at depths from about 4,000 ft to 9,000 ft below surface level, 36 the Floyd thickens toward the northeast, with a maximum thickness of about 600 ft, and has a TOC percent weight of about 1.8. The Floyd is believed to be the source rock for the conventional reservoirs in the area. 32 Carrizo Oil and Gas drilled a horizontal well in the Floyd in July 2007,37 and Murphy Oil drilled several wells in 2006. 38 With minimal news concerning the Floyd in 2008, play activity seems to have slowed down.

New Albany.

Found in the Illinois Basin, the New Albany Shale is a mostly Devonian-aged formation (the top few feet of the unit are Mississippian) that spans Kentucky, Indiana and, to a smaller extent, Illinois. The New Albany can be correlated with the Antrim Shale of Michigan and Indiana, and the Chattanooga Shale of Tennessee. 39 The New Albany gas play has been focused in Kentucky and southeastern Indiana. Formation thickness varies-the shale is about 100 to 140 ft thick in southeastern Indiana and almost 340 ft thick farther southwest in the Illinois Basin. 40 The USGS released a report in 2007 on the Illinois Basin that assessed the undiscovered, technically recoverable gas resources of the New Albany Shale at 3.79 Tcf. 41 Aurora Oil and Gas reported an average production of 424 Mcfd from their New Albany holdings in the first quarter 2008. 42 CNX Gas drilled six wells in the New Albany in 2007 to determine reservoir information and future drilling locations. 34

As the Barnett proves to be continually successful, shale plays, oil and gas, are looking to be important in the future.
There are already whispers of the Haynesville being the next Barnett, and although those rumors have been heard before about other plays, expect to hear about the Haynesville, and the Bakken and Marcellus, in the months to come.

LITERATURE CITED
1 “Core leasing area: Haynesville Shale map,” Haynesville Shale Map, http://haynesvilleshalemap.com/, accessed July 7, 2008.

2 Welborn, V., “What is the Haynesville Shale?” Shreveport Times , July 7, 2008.

3 “Shale gas fever drives land drilling in US,” Platts Oilgram News , July 4, 2008, pg. 6.


4 “Chesapeake and PXP announce Haynesville Shale joint venture,” Yahoo Financial News, July 1, 2008, http://bix.yahoo.com/bw/080701/20080701006524.html, accessed July 8, 2007.

5 “Petrohawk Energy Corporation reports Haynesville Shale result and leasehold update,” Fox Business, June 30, 2008, http://www.foxbusiness.com/story/markets/industries/energy/petrohawk-energy-corporation-reports-haynesville-shale-result-leasehold-update/, accessed July 8, 2008.

6 “Forest Oil increases holdings in E. Texas, N. La,” Forbes.com, June 30, 2008, http://www.forbes.com/feeds/ap/2008/06/30/ap5169765.html, accessed July 10, 2008.

7 “GMX Resources Inc. announces Haynesville/Bossier Shale drilling to begin 3Q08,” Prime Newswire, July 7, 2008, http://www.primenewswire.com/newsroom/news.html?d=145868, accessed July 10, 2008.

8 Fuquay, J., “Chesapeake, EnCana, boost activity in Louisiana gas shale,” Star-Telegram , June 16, 2008.

9 Brown, D., “Barnett may have Arkansas cousin,” AAPG Explorer , Feb. 2006.


10 “The Fayetteville Shale play: A geologic overview,” Arkansas Business.com, Aug. 27, 2007, http://www.arkansasbusiness.com/article.aspx?aID=99154, accessed July 8, 2008.

11 Shelby, P., “Fayetteville Shale play of North-Central Arkansas: A project update,” presented at the AAPG Annual Convention, San Antonio, Texas, April 20-23, 2008.


12 “Baker Hughes US rig count- Summary report,” Baker Hughes- Investor relations- Rig counts, http://164.109.37.157/Reports/StandardReport.aspx, accessed July 11, 2008.

13 “Fayetteville Shale play,” Southwestern Energy Company, http://www.swn.com/operations/fayetteville.shale.asp, accessed July 8, 2008.

14 “Chesapeake reports Haynesville Shale discovery in Louisiana and announces CapEx increase,” OilVoice, March 24, 2008, http://www.oilvoice.com/n/Chesapeake_Reports_Haynesville_Shale_Discovery_in_Louisiana_and_Announces_CapEx_Increase/92f01da5.aspx, accessed July 11, 2008.

15 US Department of the Interior, US Geological Society, “Assessment of undiscovered oil and gas resources of the Appalachian Basin Province, 2002,” USGS Fact Sheet FS-009-03, February 2003.

16 Durham, L. S., “Another shale making seismic waves,” AAPG Explorer, March 2008.

17 Mayhood, K., “Low down, rich and stingy,” The Columbus Dispatch , March 11, 2008.

18 Milici, R. C. and C. S. Swezey, “Assessment of Appalachian Basin oil and gas resources: Devonian Shale- Middle and Upper Paleozoic total petroleum system,” Open file report series 2006-1237, USGS Reston, Virginia, 2006, pp.38-39.

19 “Range announces record first quarter results,” OilVoice, April 24, 2008, http://www.oilvoice.com/n/Range_Announces_Record_First_Quarter_Results/4c59a7ac.aspx, accessed July 11, 2008.

20 “Atlas Energy Resources, LLC increases estimated reserve potential from Marcellus Shale to between 4 and 6 Tcf,” Reuters, Feb. 21, 2008, http://www.reuters.com/article/pressRelease/idUS127932+21-Feb-2008+MW20080221, accessed July 14, 2008.

21 Brown, D., “Big potential boost the Woodford,” AAPG Explorer , July 2008.

22 Comer, J. B., “Reservoir characteristics and production potential of the Woodford Shale,” World Oil , August 2008, pp. 83.

23 “Newfield Exploration announces 2008 capital program,” Reuters, Feb. 4, 2008, http://www.reuters.com/article/pressRelease/idUS139442+04-Feb-2008+PRN20080204, accessed July 11, 2008.

24 Hayden, J. and D. Pursell, “The Barnett Shale: Visitors guide to the hottest gas play in the US,” Tudor Pickering, Oct. 2005, http://www.tudorpickering.com/pdfs/TheBarnettShaleReport.pdf, accessed July 10, 2008.

25 “Number of vertical and horizontal producer wells in the Barnett Shale as of Jan. 1, 2008,” Powell Barnett Shale Newsletter , March 27, 2008, http://www.barnetshalenews.com/documents/VHchart%201-1-08.pdf, accessed July 10, 2008.

26 “Operations- Barnett Shale,” Devon Energy, http://www.devonenergy.com/Operation/FeatuerStories/Pages/barnett_shale.aspx, accessed July 10, 2008.


27 Cohen, D. M., “USGS names Bakken play the largest oil accumulation in the Lower 48,” World Oil , June 2008, pp. 83-84.

28 Paktinat, J., Pinkhouse, J., Fontaine, J., Lash, G. and G. Penny, “Investigation of methods to improve Utica Shale hydraulic fracturing in the Appalachian Basin,” presented at the AAPG Annual Convention, San Antonio, Texas, April 20-23, 2008.


29 “Forest Oil announces significant gas discovery in Utica Shale…” Reuters, April 1, 2008, http://www.reuters.com/article/pressRelease/idUS134787+01-Apr-2008+BW20080401, accessed July 11, 2008.

30 “Chattanooga Shale natural gas field,” Oil Shale Gas, http://www.oilshalegas.com/chattanoogashale.com, accessed July 9, 2008.

31 “AMI Project,” Irvine Energy PLC, http://www.irvineenergy.com/projects/index.htm, accessed July 9, 2008.

32 USGS Black Warrior Basin Province assessment team, “Geologic assessment of undiscovered oil and gas resources of the Black Warrior Basin Province, Alabama and Mississippi,” Hatch, J. R. and M. J. Pawlewicz, compilers, USGS Digital Data Series DDS-69-I, 2007, 76 p.

33 “Domestic Energy announces Appalachian Shale plan,” Reuters, April 28, 2008, http://www.reuters.com/article/preeRelease/idUS139048+28-Apr-2008+MW20080428, accessed July 9, 2008.

34 “CNX Gas reports fourth quarter and full year 2007 results,” Reuters, Jan. 29, 2008, http://www.reuters.com/article/pressRelease/idUS140410+29-Jan-2008+PRN20080129, accessed July 11, 2008.

35 “Atlas Energy announces four successful horizontal wells in Tennessee’s Chattanooga Shale, and a net acreage position of 105,000 acres in the play,” OilVoice, June 21, 2008, http://www.oilvoice.com/n/Atlas_Energy_Announces_Four_Successful_Horizontal_Wells_in_Tennessees_Chattanooga_Shale/9fc6bbe0.aspx, accessed July 9, 2008.

36 “Floyd Shale potential of the Black Warrior Basin: Executive summary,” Mississippi Geological Society eBulletin , Vol. 55, No. 7, March 2007.


37 “Carrizo Oil & Gas, Inc. announces record production and third quarter 2007 financial results,” Carrizo Oil & Gas, Nov. 8, 2007, http://carrizo.mediaroom.com/index.php?s=43&iten=154, accessed July 10, 2008.

38 Edmonds, C., “New shales may be ready to deliver,” The Street, Feb. 22, 2007, http://www.thestreet.com/story/10340267/1/new-shales-may-be-ready-to-deliver.html, accessed July 10, 2008.


39 “New Albany Shale,” Indiana Geological Survey, http://igs.indiana.edu/Geology/structure/compendium/html/comp82hw.cfm, accessed July 9, 2008.


40 Comer, J. B., Hasenmueller, N. R., Mastalerz, M. D., Rupp, J. A., Shaffer, N. R. and C. W. Zuppann, “The New Albany Shale gas play in southern Indiana,” presented at AAPG Eastern Section Meeting, Buffalo, N.Y., Oct. 8-11, 2006.

41 US Department of the Interior, US Geological Survey, “Assessment of undiscovered oil and gas resources of the Illinois Basin, 2007,” USGS Fact Sheet 2007-3058, August 2007.

42 “Aurora Oil & Gas Corp. announces first quarter 2008 results,” Reuters, May 9, 2008, http://www.reuters.com/article/pressRelease/idUS248894+09-May-2008+PRN20080509, accessed July 11, 2008.

Thursday, August 14, 2008

Geology And Resources Of Some Oil Shales

In my first job as a geologist, I worked with John Dyni doing field and laboratory work studying the oil shale in Colorado and Utah for the USGS. I'm not sure if anyone knows when, and to what degree these oil shale deposits will be economically feasible to develop. There are many questions that must be addressed, such as environmental damage, water usage, etc. The following article is a good summary about oil shales of the world.
Peter

Geology and Resources of Some World Oil-Shale Deposits
Reprint of: USGS Scientific Investigations Report 2005-5294
By John R. Dyni
Introduction
Oil shale is commonly defined as a fine-grained sedimentary rock containing organic matter that yields substantial amounts of oil and combustible gas upon destructive distillation. Most of the organic matter is insoluble in ordinary organic solvents; therefore, it must be decomposed by heating to release such materials. Underlying most definitions of oil shale is its potential for the economic recovery of energy, including shale oil and combustible gas, as well as a number of byproducts. A deposit of oil shale having economic potential is generally one that is at or near enough to the surface to be developed by open-pit or conventional underground mining or by in-situ methods.

Oil shales range widely in organic content and oil yield. Commercial grades of oil shale, as determined by their yield of shale oil, ranges from about 100 to 200 liters per metric ton (l/t) of rock. The U.S. Geological Survey has used a lower limit of about 40 l/t for classification of Federal oil-shale lands. Others have suggested a limit as low as 25 l/t.Deposits of oil shale are in many parts of the world. These deposits, which range from Cambrian to Tertiary age, may occur as minor accumulations of little or no economic value or giant deposits that occupy thousands of square kilometers and reach thicknesses of 700 m or more.

Oil shales were deposited in a variety of depositional environments, including fresh-water to highly saline lakes, epicontinental marine basins and subtidal shelves, and in limnic and coastal swamps, commonly in association with deposits of coal.In terms of mineral and elemental content, oil shale differs from coal in several distinct ways. Oil shales typically contain much larger amounts of inert mineral matter (60–90 percent) than coals, which have been defined as containing less than 40 percent mineral matter.

The organic matter of oil shale, which is the source of liquid and gaseous hydrocarbons, typically has a higher hydrogen and lower oxygen content than that of lignite and bituminous coal.In general, the precursors of the organic matter in oil shale and coal also differ. Much of the organic matter in oil shale is of algal origin, but may also include remains of vascular land plants that more commonly compose much of the organic matter in coal. The origin of some of the organic matter in oil shale is obscure because of the lack of recognizable biologic structures that would help identify the precursor organisms. Such materials may be of bacterial origin or the product of bacterial degradation of algae or other organic matter.

The mineral component of some oil shales is composed of carbonates including calcite, dolomite, and siderite, with lesser amounts of aluminosilicates. For other oil shales, the reverse is true—silicates including quartz, feldspar, and clay minerals are dominant and carbonates are a minor component. Many oil-shale deposits contain small, but ubiquitous, amounts of sulfides including pyrite and marcasite, indicating that the sediments probably accumulated in dysaerobic to anoxic waters that prevented the destruction of the organic matter by burrowing organisms and oxidation.

Although shale oil in today’s (2004) world market is not competitive with petroleum, natural gas, or coal, it is used in several countries that possess easily exploitable deposits of oil shale but lack other fossil fuel resources. Some oil-shale deposits contain minerals and metals that add byproduct value such as alum [KAl(SO4)2•12H2O], nahcolite (NaHCO3), dawsonite [NaAl(OH)2CO3], sulfur, ammonium sulfate, vanadium, zinc, copper, and uranium.The gross heating value of oil shales on a dry-weight basis ranges from about 500 to 4,000 kilocalories per kilogram (kcal/kg) of rock. The high-grade kukersite oil shale of Estonia, which fuels several electric power plants, has a heating value of about 2,000 to 2,200 kcal/kg. By comparison, the heating value of lignitic coal ranges from 3,500 to 4,600 kcal/kg on a dry, mineral-free basis (American Society for Testing Materials, 1966).

Tectonic events and volcanism have altered some deposits. Structural deformation may impair the mining of an oil-shale deposit, whereas igneous intrusions may have thermally degraded the organic matter. Thermal alteration of this type may be restricted to a small part of the deposit, or it may be widespread making most of the deposit unfit for recovery of shale oil.

The purpose of this report is to (1) discuss the geology and summarize the resources of selected deposits of oil shale in varied geologic settings from different parts of the world and (2) present new information on selected deposits developed since 1990 (Russell, 1990).

Recoverable Resources
The commercial development of an oil-shale deposit depends upon many factors. The geologic setting and the physical and chemical characteristics of the resource are of primary importance. Roads, railroads, power lines, water, and available labor are among the factors to be considered in determining the viability of an oil-shale operation. Oil-shale lands that could be mined may be preempted by present land usage such as population centers, parks, and wildlife refuges.

Development of new in-situ mining and processing technologies may allow an oil-shale operation in previously restricted areas without causing damage to the surface or posing problems of air and water pollution.The availability and price of petroleum ultimately effect the viability of a large-scale oil-shale industry. Today, few, if any deposits can be economically mined and processed for shale oil in competition with petroleum. Nevertheless, some countries with oil-shale resources, but lack petroleum reserves, find it expedient to operate an oil-shale industry. As supplies of petroleum diminish in future years and costs for petroleum increase, greater use of oil shale for the production of electric power, transportation fuels, petrochemicals, and other industrial products seems likely.

Determining Grade of Oil Shale
The grade of oil shale has been determined by many different methods with the results expressed in a variety of units. The heating value of the oil shale may be determined using a calorimeter. Values obtained by this method are reported in English or metric units, such as British thermal units (Btu) per pound of oil shale, calories per gram (cal/gm) of rock, kilocalories per kilogram (kcal/kg) of rock, megajoules per kilogram (MJ/kg) of rock, and other units. The heating value is useful for determining the quality of an oil shale that is burned directly in a power plant to produce electricity. Although the heating value of a given oil shale is a useful and fundamental property of the rock, it does not provide information on the amounts of shale oil or combustible gas that would be yielded by retorting (destructive distillation).

The grade of oil shale can be determined by measuring the yield of oil of a shale sample in a laboratory retort. This is perhaps the most common type of analysis that is currently used to evaluate an oil-shale resource. The method commonly used in the United States is called the “modified Fischer assay,” first developed in Germany, then adapted by the U.S. Bureau of Mines for analyzing oil shale of the Green River Formation in the western United States (Stanfield and Frost, 1949). The technique was subsequently standardized as the American Society for Testing and Materials Method D-3904-80 (1984). Some laboratories have further modified the Fischer assay method to better evaluate different types of oil shale and different methods of oil-shale processing.The standardized Fischer assay method consists of heating a 100-gram sample crushed to –8 mesh (2.38-mm mesh) screen in a small aluminum retort to 500ºC at a rate of 12ºC per minute and held at that temperature for 40 minutes. The distilled vapors of oil, gas, and water are passed through a condenser cooled with ice water into a graduated centrifuge tube. The oil and water are then separated by centrifuging. The quantities reported are the weight percentages of shale oil (and its specific gravity), water, shale residue, and “gas plus loss” by difference.

The Fischer assay method does not determine the total available energy in an oil shale. When oil shale is retorted, the organic matter decomposes into oil, gas, and a residuum of carbon char remaining in the retorted shale. The amounts of individual gases—chiefly hydrocarbons, hydrogen, and carbon dioxide—are not normally determined but are reported collectively as “gas plus loss,” which is the difference of 100 weight percent minus the sum of the weights of oil, water, and spent shale.

Some oil shales may have a greater energy potential than that reported by the Fischer assay method depending on the components of the “gas plus loss.”The Fischer assay method also does not necessarily indicate the maximum amount of oil that can be produced by a given oil shale. Other retorting methods, such as the Tosco II process, are known to yield in excess of 100 percent of the yield reported by Fischer assay. In fact, special methods of retorting, such as the Hytort process, can increase oil yields of some oil shales by as much as three to four times the yield obtained by the Fischer assay method (Schora and others, 1983; Dyni and others, 1990).

At best, the Fischer assay method only approximates the energy potential of an oil-shale deposit.Newer techniques for evaluating oil-shale resources include the Rock-Eval and the “material-balance” Fischer assay methods. Both give more complete information about the grade of oil shale, but are not widely used. The modified Fischer assay, or close variations thereof, is still the major source of information for most deposits.It would be useful to develop a simple and reliable assay method for determining the energy potential of an oil shale that would include the total heat energy and the amounts of oil, water, combustible gases including hydrogen, and char in sample residue.

Origin of Organic Matter
Organic matter in oil shale includes the remains of algae, spores, pollen, plant cuticle and corky fragments of herbaceous and woody plants, and other cellular remains of lacustrine, marine, and land plants. These materials are composed chiefly of carbon, hydrogen, oxygen, nitrogen, and sulfur. Some organic matter retains enough biological structures so that specific types can be identified as to genus and even species. In some oil shales, the organic matter is unstructured and is best described as amorphous (bituminite). The origin of this amorphous material is not well known, but it is likely a mixture of degraded algal or bacterial remains. Small amounts of plant resins and waxes also contribute to the organic matter.

Fossil shell and bone fragments composed of phosphatic and carbonate minerals, although of organic origin, are excluded from the definition of organic matter used herein and are considered to be part of the mineral matrix of the oil shale.Most of the organic matter in oil shales is derived from various types of marine and lacustrine algae. It may also include varied admixtures of biologically higher forms of plant debris that depend on the depositional environment and geographic position. Bacterial remains can be volumetrically important in many oil shales, but they are difficult to identify.

Most of the organic matter in oil shale is insoluble in ordinary organic solvents, whereas some is bitumen that is soluble in certain organic solvents. Solid hydrocarbons, including gilsonite, wurtzilite, grahamite, ozokerite, and albertite, are present as veins or pods in some oil shales. These hydrocarbons have somewhat varied chemical and physical characteristics, and several have been mined commercially.

Thermal Maturity of Organic Matter
The thermal maturity of an oil shale refers to the degree to which the organic matter has been altered by geothermal heating. If the oil shale is heated to a high enough temperature, as may be the case if the oil shale were deeply buried, the organic matter may thermally decompose to form oil and gas. Under such circumstances, oil shales can be source rocks for petroleum and natural gas.

The Green River oil shale, for example, is presumed to be the source of the oil in the Red Wash field in northeastern Utah. On the other hand, oil-shale deposits that have economic potential for their shale-oil and gas yields are geothermally immature and have not been subjected to excessive heating. Such deposits are generally close enough to the surface to be mined by open-pit, underground mining, or by in-situ methods.

The degree of thermal maturity of an oil shale can be determined in the laboratory by several methods. One technique is to observe the changes in color of the organic matter in samples collected from varied depths in a borehole. Assuming that the organic matter is subjected to geothermal heating as a function of depth, the colors of certain types of organic matter change from lighter to darker colors. These color differences can be noted by a petrographer and measured using photometric techniques.

Geothermal maturity of organic matter in oil shale is also determined by the reflectance of vitrinite (a common constituent of coal derived from vascular land plants), if present in the rock. Vitrinite reflectance is commonly used by petroleum explorationists to determine the degree of geothermal alteration of petroleum source rocks in a sedimentary basin. A scale of vitrinite reflectances has been developed that indicates when the organic matter in a sedimentary rock has reached temperatures high enough to generate oil and gas. However, this method can pose a problem with respect to oil shale, because the reflectance of vitrinite may be depressed by the presence of lipid-rich organic matter.Vitrinite may be difficult to recognize in oil shale because it resembles other organic material of algal origin and may not have the same reflectance response as vitrinite, thereby leading to erroneous conclusions. For this reason, it may be necessary to measure vitrinite reflectance from laterally equivalent vitrinite-bearing rocks that lack the algal material.In areas where the rocks have been subjected to complex folding and faulting or have been intruded by igneous rocks, the geothermal maturity of the oil shale should be evaluated for proper determination of the economic potential of the deposit.

Classification of Oil Shale
Oil shale has received many different names over the years, such as cannel coal, boghead coal, alum shale, stellarite, albertite, kerosene shale, bituminite, gas coal, algal coal, wollongite, schistes bitumineux, torbanite, and kukersite. Some of these names are still used for certain types of oil shale. Recently, however, attempts have been made to systematically classify the many different types of oil shale on the basis of the depositional environment of the deposit, the petrographic character of the organic matter, and the precursor organisms from which the organic matter was derived.

A useful classification of oil shales was developed by A.C. Hutton (1987, 1988, 1991), who pioneered the use of blue/ultraviolet fluorescent microscopy in the study of oil-shale deposits of Australia. Adapting petrographic terms from coal terminology, Hutton developed a classification of oil shale based primarily on the origin of the organic matter. His classification has proved to be useful for correlating different kinds of organic matter in oil shale with the chemistry of the hydrocarbons derived from oil shale.

Hutton (1991) visualized oil shale as one of three broad groups of organic-rich sedimentary rocks: (1) humic coal and carbonaceous shale, (2) bitumen-impregnated rock, and (3) oil shale. He then divided oil shale into three groups based upon their environments of deposition — terrestrial, lacustrine, and marine (fig. 1).Terrestrial oil shales include those composed of lipid-rich organic matter such as resin spores, waxy cuticles, and corky tissue of roots, and stems of vascular terrestrial plants commonly found in coal-forming swamps and bogs. Lacustrine oil shales include lipid-rich organic matter derived from algae that lived in freshwater, brackish, or saline lakes. Marine oil shales are composed of lipid-rich organic matter derived from marine algae, acritarchs (unicellular organisms of questionable origin), and marine dinoflagellates.

Several quantitatively important petrographic components of the organic matter in oil shale—telalginite, lamalginite, and bituminite—are adapted from coal petrography. Telalginite is organic matter derived from large colonial or thick-walled unicellular algae, typified by genera such as Botryococcus. Lamalginite includes thin-walled colonial or unicellular algae that occurs as laminae with little or no recognizable biologic structures. Telalginite and lamalginite fluoresce brightly in shades of yellow under blue/ultraviolet light.

Bituminite, on the other hand, is largely amorphous, lacks recognizable biologic structures, and weakly fluoresces under blue light. It commonly occurs as an organic groundmass with fine-grained mineral matter. The material has not been fully characterized with respect to its composition or origin, but it is commonly an important component of marine oil shales. Coaly materials including vitrinite and inertinite are rare to abundant components of oil shale; both are derived from humic matter of land plants and have moderate and high reflectance, respectively, under the microscope.

Within his three-fold grouping of oil shales (terrestrial, lacustrine, and marine), Hutton (1991) recognized six specific oil-shale types: cannel coal, lamosite, marinite, torbanite, tasmanite, and kukersite. The most abundant and largest deposits are marinites and lamosites.Cannel coal is brown to black oil shale composed of resins, spores, waxes, and cutinaceous and corky materials derived from terrestrial vascular plants together with varied amounts of vitrinite and inertinite.

Cannel coals originate in oxygen-deficient ponds or shallow lakes in peat-forming swamps and bogs (Stach and others, 1975, p. 236–237).Lamosite is pale- and grayish-brown and dark gray to black oil shale in which the chief organic constituent is lamalginite derived from lacustrine planktonic algae. Other minor components in lamosite include vitrinite, inertinite, telalginite, and bitumen.

The Green River oil-shale deposits in western United States and a number of the Tertiary lacustrine deposits in eastern Queensland, Australia, are lamosites.Marinite is a gray to dark gray to black oil shale of marine origin in which the chief organic components are lamalginite and bituminite derived chiefly from marine phytoplankton. Marinite may also contain small amounts of bitumen, telalginite, and vitrinite. Marinites are deposited typically in epeiric seas such as on broad shallow marine shelves or inland seas where wave action is restricted and currents are minimal.

The Devonian–Mississippian oil shales of eastern United States are typical marinites. Such deposits are generally widespread covering hundreds to thousands of square kilometers, but they are relatively thin, often less than about 100 m.Torbanite, tasmanite, and kukersite are related to specific kinds of algae from which the organic matter was derived; the names are based on local geographic features. Torbanite, named after Torbane Hill in Scotland, is a black oil shale whose organic matter is composed mainly of telalginite derived largely from lipid-rich Botryococcus and related algal forms found in fresh- to brackish-water lakes. It also contains small amounts of vitrinite and inertinite. The deposits are commonly small, but can be extremely high grade. Tasmanite, named from oil-shale deposits in Tasmania, is a brown to black oil shale. The organic matter consists of telalginite derived chiefly from unicellular tasmanitid algae of marine origin and lesser amounts of vitrinite, lamalginite, and inertinite. Kukersite, which takes its name from Kukruse Manor near the town of Kohtla-Järve, Estonia, is a light brown marine oil shale. Its principal organic component is telalginite derived from the green alga, Gloeocapsomorpha prisca. The Estonian oil-shale deposit in northern Estonia along the southern coast of the Gulf of Finland and its eastern extension into Russia, the Leningrad deposit, are kukersites.

Evaluation of Oil-Shale Resources
Relatively little is known about many of the world’s deposits of oil shale and much exploratory drilling and analytical work need to be done. Early attempts to determine the total size of world oil-shale resources were based on few facts, and estimating the grade and quantity of many of these resources were speculative, at best. The situation today has not greatly improved, although much information has been published in the past decade or so, notably for deposits in Australia, Canada, Estonia, Israel, and the United States.

Evaluation of world oil-shale resources is especially difficult because of the wide variety of analytical units that are reported. The grade of a deposit is variously expressed in U.S. or Imperial gallons of shale oil per short ton (gpt) of rock, liters of shale oil per metric ton (l/t) of rock, barrels, short or metric tons of shale oil, kilocalories per kilogram (kcal/kg) of oil shale, or gigajoules (GJ) per unit weight of oil shale. To bring some uniformity into this assessment, oil-shale resources in this report are given in both metric tons of shale oil and in equivalent U.S. barrels of shale oil, and the grade of oil shale, where known, is expressed in liters of shale oil per metric ton (l/t) of rock. If the size of the resource is expressed only in volumetric units (barrels, liters, cubic meters, and so on), the density of the shale oil must be known or estimated to convert these values to metric tons. Most oil shales produce shale oil that ranges in density from about 0.85 to 0.97 by the modified Fischer assay method. In cases where the density of the shale oil is unknown, a value of 0.910 is assumed for estimating resources.

Byproducts may add considerable value to some oil-shale deposits. Uranium, vanadium, zinc, alumina, phosphate, sodium carbonate minerals, ammonium sulfate, and sulfur are some of the potential byproducts. The spent shale after retorting is used to manufacture cement, notably in Germany and China. The heat energy obtained by the combustion of the organic matter in oil shale can be used in the cement-making process. Other products that can be made from oil shale include specialty carbon fibers, adsorbent carbons, carbon black, bricks, construction and decorative blocks, soil additives, fertilizers, rock wool insulating material, and glass. Most of these uses are still small or in experimental stages, but the economic potential is large.

This appraisal of world oil-shale resources is far from complete. Many deposits are not reviewed because data or publications are unavailable. Resource data for deeply buried deposits, such as a large part of the Devonian oil-shale deposits in eastern United States, are omitted, because they are not likely to be developed in the foreseeable future.

(Wrong! The Devonian "oil shales" , like the Barnett and the Marcellus Shales are producing gas through new technology, search this blog for more information. Peter)

Thus, the total resource numbers reported herein should be regarded as conservative estimates. This review focuses on the larger deposits of oil shale that are being mined or have the best potential for development because of their size and grade.

United States of America Oil Shale
Figure 16. Areas underlain by the Green River Formation in Colorado, Utah, and Wyoming, United States. Figure 18. Paleogeographic map showing shoreline of the Late Devonian sea in eastern United States and major areas of surface-mineable Devonian oil shale. After Conant and Swanson (1961, their fig. 13) and Matthews and others (1980, their fig. 5).


Australia Oil Shale
Figure 2. Deposits of oil shale in Australia. From Crisp and others (1987, their fig. 1). Area of Toolebuc oil shale from Cook and Sherwood (1989, their fig. 2).

Brazil Oil Shale
Figure 3. Deposits of oil shale in Brazil. From Padula (1969, his fig. 1).
Canada Oil Shale
Figure 5. Oil-shale deposits in Canada. Adapted from Macauley (1981).
Estonia and Sweden Oil Shale
Figure 8. Location of the kukersite deposits in northern Estonia and Russia. Adapted from Kattai and Lokk (1998, their fig. 1) and Bauert (1994, his fig. 3).Figure 14. Map showing areas of Alum Shale in Sweden. Adapted from Andersson and others (1985, their fig. 3). Areas in blue are lakes.

Israel and Jordan Oil Shale
Figure 10. Deposits of oil shale in Israel. From Minster (1994, his fig. 1).Figure 11. Oil-shale deposits in Jordan. Adapted from Jaber and others (1997, their fig. 1) and Hamarneh (1998, his figure on p. 4).

Morocco Oil Shale
Figure 12. Oil-shale deposits in Morocco. From Bouchta (1984, his fig. 1).

China, Russia, Syria, Thailand and Turkey
Other countries with oil shales.

Wednesday, August 13, 2008

Haynesville Shale Gas Play, North Louisiana and East Texas

Here is some information on a newly economic shale gas play. It warrants watching closely.
Peter
source


Haynesville Shale: News, Map, Videos, Lease and Royalty Information
Haynesville Shale
Haynesville Shale Orientation:
The Haynesville Shale, is a black, organic-rich shale of Upper Jurassic age that underlies much of the Gulf Coast area of the United States. "Haynesville Shale" is a drillers term for shale rock units within the Haynesville Formation. The Haynesville Formation is underlain by the Smackover Formation and overlain by rocks of the Cotton Valley Group. It was deposited about 150 million years ago in a shallow offshore environment.

Geologists have long known that the Haynesville Formation contained natural gas. However, because of its low permeability the Haynesville was originally considered to be a gas source rock rather than a gas reservoir. Today, natural gas production from the Haynesville occurs from rocks about two miles beneath northwestern Louisiana, southwestern Arkansas and eastern Texas. The most productive areas have been Caddo, Bienville, Bossier, DeSoto, Red River and Webster Parishes of Louisiana plus adjacent areas in southwest Arkansas and east Texas.

Quote: Louisiana DOE
“This is an extraordinary time for Louisiana, particularly in north Louisiana, where we are experiencing something akin to a modern day gold rush due to excitement about the Haynesville Shale discovery. To put the magnitude of this sale into perspective: This month’s lease sale surpassed by more than double the bonus collections for the previous 11 months of FY 2007-08 combined, almost entirely because of activity in north Louisiana... 25 of the 38 leases awarded were from Caddo, Red River and Bienville parishes, totaling approximately $34 million in cash payments, and the average bonus per acre for these leases was over $13,400 per acre, while more typical prices in the past for north Louisiana have been around $400 per acre." (source)

Quote: Chesapeake Energy
“Based on its geoscientific, petrophysical and engineering research during the past two years and the results of three horizontal and four vertical wells it has drilled, Chesapeake believes the Haynesville Shale play could potentially have a larger impact on the company than any other play in which it has participated to date." (source)

News Reports
Haynesville Shale News: ShaleBlog.com, a blog tracking news about the Haynesville Shale.

Other Shale Resources
Marcellus Shale: Very similar to the Haynesville. The Marcellus Shale is a new gas resource of the Appalachian Basin.

Barnett Shale: Here's where it all started. The Barnett Shale of Texas was where the hydrofrac and horizontal drilling techniques were first mastered for tight shale reservoirs.

Fayetteville Shale: Another gas shale formation producing in northern Arkansas..

Oil and Gas Jobs
Oil and Gas Job Opportunties: Multiple shale plays happening across the United States have triggered an enormous demand for skilled workers and trainees.

Haynesville Stratigraphy

Gas production is mainly in the Haynesville Formation. However, some gas is also produced from the Cotton Valley Group and Smackover Formation.

Government & Regulatory
Questions and Answers About the Haynesville Shale: Answers from the Shreveport Mayor's Office about leases, landmen, signing bonus, royalties and drilling activities.

Louisiana Office of Mineral Resources: Monthly lease information and access to mineral resource records. Historical oil and gas production data. Historical lease and royalty data.

Louisiana Department of Natural Resources: Department "news" page.

Haynesville Economics
Economic Impact: Local officials of Shreveport get in touch with counterparts in Fort Worth to find out what they learned from their Barnett Shale experience.

Chesapeake Rig Tour: KSLA video showing a drill rig with details on the horizontal well technique.

Waiting to Sign: Property owners are uniting and holding out for the best deal possible. Their supergroup represents 6000 owners. They have an offer of $27,200 per acre signing bonus plus 26% royalty.

Advice for Property Owners: There are many sources of advice on leasing a natural gas property. This video explores the options that landowners have for advice.

Gas Lease and Royalty
Gas Lease Forum: Knowledge is power when you receive an offer to lease your land. Find out what others are being offered and share advice at this forum.

Natural Gas Lease Database: See how much was paid as a signing bonus to numerous landowners in most counties. Includes transaction date, signing bonus per acre, term of lease, royalty rate and number of acres. Share your information anonymously to help others.

National Association of Royalty Owners: The only national organization representing, solely and without compromise, oil and gas royalty owners interests.

Wellhead Price of Natural Gas: Current and historical price data from the US Energy Information Administration.

Gas Lease Blog: Information on natural gas development and leases.

Glossary of Natural Gas Leasing Terms: Look up definitions to understand your lease or whatever you are reading.

Gas Leasing FAQ's: Some of the best questions answered right here.

Geology News
Daily news for geology and earth science. Delivered to you free by RSS or email.

Haynesville Shale Map
Drilling activity in the Haynesville Shale has been most active in Caddo, Bossier, DeSoto and Webster Parishes, Louisiana plus adjacent areas in southwest Arkansas and east Texas. The Shreveport Times has a well location map for Louisiana.

Estimate Your Royalty
Natural Gas Royalty Estimator: Enter data from your lease agreement and make a few assumptions. Unoffical estimates of your annual royalty payments.

Wellhead Price History
The wellhead price of natural gas changes in response to market and political forces.

Haynesville Drilling
The productive potential of the Haynesville Shale was not fully realized until horizontal drilling and hydrofracing technologies were demonstrated in other unconventional shale reservoirs. The hydrofracing process helps liberate gas from the shale and horizontal drilling allows a single well to drain a much larger volume of rock than a traditional vertical well.

Unconventional Gas Technology:A "white paper" by Schlumberger, the well service company. Explains how hydraulic fracturing is used to stimulate production in tight gas shale reservoirs. (large .pdf file)

How Much Water is Needed? Frac jobs require a lot of water. Here's some experience on water needs from the Barnett Shale of Texas..

Interactive Drill Rig: Learn about drill rigs and drilling with this interactive presentation by Dale Energy.

Night-Time Satellite Photos Of Earth

Night-time energy usage around the world. Who and where are the people burning the "midnight oil"? What does this say about geography, industry, population, and civilization?
Fascinating. It is a big world.
Peter
(source)

"Satellite Photo of Earth at Night"Shown below is a famous NASA image that is often called a "satellite photo of earth at night". It isn't really a "photo". Instead it is an image that was compiled using data from the Defense Meteorological Satellite Program. It is a map of the location of permanent lights on Earth's surface. Each white dot on the map represents the light of a city. The entire image is show below and we follow it with enlarged continents and commentary.
This map shows the geographic distribution of cities. It clearly shows that cities are concentrated in Europe, the eastern United States, Japan, China and India. It is a better map for showing the geography of night time electricity consumption for outdoor lighting than it is for showing the geography of population. For example: the eastern United States is very bright but the more densely populated areas of China and India are not nearly as bright in this image. NASA Image.



This map shows the geographic distribution of night time lights in the United States, Canada, Mexico and the Caribbean. Strong lights occur in a strand that includes Washington, DC, Philadelphia, New Jersey, New York City and Boston. Most of the large cities of Canada are located within a couple hundred miles of the United States border. Chicago stands out on the shoreline of Lake Michigan and other major cities in the central states are collected by a network of highways. On the west coast, Seattle, San Francisco, Los Angeles and San Diego stand out. The coastlines of Florida and Puerto Rico are lined with bright cities. Finally, the cities of Hawaii and oil facilities of the north Alaska coast are also "visible from space". NASA Image.

Western Europe is aglow with night lights. This image clearly shows that the cities of Europe are along the coasts. The Mediterranean coasts of Italy, France and Spain are a solid line of light as is the southern shorelines of the Black and Caspian Seas. The Sahara of northern Africa and the jungles of south-central Africa are largely void of illuminated cities. One of the most striking features on this image is the high concentration of cities on the Nile River, downstream from the Aswan Dam. NASA Image.


The cities of South America are mainly concentrated on the southwestward-facing Atlantic coast, along the Pacific coast and northern Colombia and Venezuela. Large areas of the Amazon Basin are without bright cities and some of the night lights there might actually be the fires if deforestation and agricultural burning. NASA Image.


Japan stands out on this satellite view of Asia at night, along with the west coast of Taiwan, South Korea, Hong Kong and Bangkok. The route of the Trans-Siberian Railroad can be seen as a light line across the otherwise dark area of northern Russia. High city densities in eastern China, Indonesia, India and the eastern coast of Australia can clearly be seen. NASA Image

Marcellus Shale And Natural Gas Production In The NE United States

The successful production of large volumes of natural gas from shale rocks has enormously positive economic consequences for America, and indeed, the world. This is a relatively recent development of extreme importance. For an idea of how important natural gas is, consider exactly what it is and its many uses:

Natural gas is a gaseous fossil fuel consisting primarily of methane but including significant quantities of ethane, propane, butane, and pentane—heavier hydrocarbons removed prior to use as a consumer fuel —as well as carbon dioxide, nitrogen, helium and hydrogen sulfide.[1] It is found in oil fields (associated) either dissolved or isolated in natural gas fields (non-associated), and in coal beds (as coalbed methane).

This so-called "Shale Gas" and the Marcellus Shale development warrants close attention.
Peter
(source)

Marcellus Shale - Appalachian Basin Natural Gas Play
New research results surprise everyone on the potential of this well-known Devonian black shale.
Super Giant Field in the Appalachians?A few years ago every geologist involved in Appalachian Basin oil and gas knew about the Devonian black shale called the Marcellus. Its black color made it easy to spot in the field and its slightly radioactive signature made it a very easy pick on a geophysical well log. However, very few of these geologists were excited about the Marcellus Shale as a major source of natural gas. Wells drilled through it produced some gas but rarely in enormous quantity. Few if any in the natural gas industry suspected that the Marcellus might soon be a major contributor to the natural gas supply of the United States - large enough to be spoken of as a "super giant" gas field.

Early Marcellus Estimates by USGSAs recently as 2002 the United States Geological Survey in its Assessment of Undiscovered Oil and Gas Resources of the Appalachian Basin Province, calculated that the Marcellus Shale contained an estimated undiscovered resource of about 1.9 trillion cubic feet of gas. [1] That's a lot of gas but spread over the enormous geographic extent of the Marcellus it was not that much per acre.

The First Hints of Big Production
Range Resources - Appalachia, LLC may have started the Marcellus Shale gas play. In 2003 they drilled a Marcellus well in Washington County, Pennsylvania and found a promising flow of natural gas [2]. They experimented with drilling and hydraulic fracturing methods that worked in the Barnett Shale of Texas. Their first Marcellus gas production from the well began in 2005. Between then and the end of 2007 more than 375 gas wells with suspected Marcellus intent had been permitted in Pennsylvania [2].

Recent Surprise EstimatesIn early 2008, Terry Englander, a geoscience professor at Pennsylvania State University, and Gary Lash, a geology professor at the State University of New York at Fredonia, surprised everyone with estimates that the Marcellus might contain more than 500 trillion cubic feet of natural gas. Using some of the same horizontal drilling and hydraulic fracturing methods that had previously been applied in the Barnett Shale of Texas, perhaps 10% of that gas (50 trillion cubic feet) might be recoverable. That volume of natural gas would be enough to supply the entire United States for about two years and have a wellhead value of about one trillion dollars! [5]


The Marcellus Shale, also referred to as the Marcellus Formation, is a Middle Devonian-age black, low density, carbonaceous (organic rich) shale that occurs in the subsurface beneath much of Ohio, West Virginia, Pennsylvania and New York. Small areas of Maryland, Kentucky, Tennessee, and Virginia are also underlain by the Marcellus Shale. See the map of the Marcellus Shale above.

How Deep is the Marcellus Shale?


Throughout most of its extent, the Marcellus is nearly a mile or more below the surface. The map at right shows the depth of the Marcellus Shale. These great depths make the Marcellus Formation a very expensive target. Successful wells must yield large volumes of gas to pay for the drilling costs that can easily exceed a million dollars for a traditional vertical well and much more for a horizontal well with hydraulic fracturing. Using the two maps together, some especially interesting areas can be seen. These are where thick Marcellus Shale can be drilled at minimum depths. Although this is a great oversimplification, it correlates with the heavy leasing activity that has occurred in parts of northern Pennsylvania and western New York.

Where is the Highest Production Potential?

Rock units are not homogeneous. The gas in the Marcellus Shale is a result of its contained organic content. Logic therefore suggests that the more organic material there is contained in the rock the greater its ability to yield gas. John Harper of the Pennsylvania Geological Survey suggests that the areas with the greatest production potential are those areas where the net thickness of organic-rich shale within the Marcellus Formation is the greatest. A map showing this distribution for the state of Pennsylvania is shown at right. Northeastern Pennsylvania is where the thick organic-rich shale intervals are located.


Low Yield, Long-Lasting Production


Before 2000, many successful natural gas wells had been completed in the Marcellus. The yields of these wells were often unimpressive upon completion. However, many of these older wells in the Marcellus have a sustained production that decreases slowly over time. Many of them continued to produce gas for several decades. A patient investor might make a profit from these low yield wells with slowly declining production rates. For new wells drilled with the new horizontal drilling and hydraulic fracturing technologies the inital production can be much higher than what was seen in the old wells. Then as production rates decline a well might receive new hydraulic fracturing treatments to boost production. The wells will eventually deplete but the fracturing treatments help to produce a more complete recovery of the natural gas. Because this method has not been applied long-term to wells in the Marcellus there is little production history data.

How Does the Gas Occur in the Rock?


Natural gas occurs within the Marcellus Shale in three ways: 1) within the pore spaces of the shale; 2) within vertical fractures (joints) that break through the shale; and, 3) adsorbed on mineral grains. Most of the recoverable gas is contained in the pore spaces. However, the gas has difficulty escaping through the pore spaces because they are very tiny and poorly connected. Most historic wells in the Marcellus produced gas at a very slow rate because of the low permeability mentioned above. This is typical for a shale. However, the most successful historic wells in the Marcellus share a common characteristic: they intersect numerous fractures. These fractures allow the gas to flow through the rock unit and into the well bore. The fractures intersecting the well also intersect other fractures and those fractures intersect still more fractures. Thus, an extensive fracture network allows one well to drain gas from a very large volume of shale. A single well can recover gas from many acres of surrounding land.


Horizontal Drilling to Penetrate More Fractures
The fractures (also known as "joints") in the Marcellus Shale are vertical. So, a vertical borehole would be expected to intersect very few of them. However, a horizontal well, drilled perpendicular to the most common fracture orientation should intersect a maximum number of fractures. The diagram to the right illustrates the concept of a horizontal well. High yield wells in the Marcellus Shale have been built using the horizontal drilling technique. Some horizontal wells in the Marcellus Shale have initial flows that suggest that they are capable of yielding millions of cubic feet of gas per day, making them some of the most productive gas wells in the eastern United States. Although some experts are very optimistic on the long-term production rates of these wells, it is too early to determine their productive life or long-term yield.

Increase the Number of Fractures
A second method is used to increase the productivity of a well. That is to increase the number of fractures in a well using a technique known as "hydraulic fracturing" or "hydrofracing". This method uses high-pressure water or a gel to induce fractures in the rock surrounding the well bore. Hydrofracing is done by sealing off a portion of the well and injecting water or gel under very high pressure into the isolated portion of the hole. The high pressure fractures the rock and pushes the fractures open. To prevent the fractures from closing when the pressure is reduced several tons of sand or other "propant" is pumped down the well and into the pressurized portion of the hole. When the fracturing occurs millions of sand grains are forced into the fractures. If enough sand grains are trapped in the fracture it will be propped partially open when the pressure is reduced. This provides an improved permeability for the flow of gas to the well.

Economic Significance of the Marcellus Shale Gas Field
The presence of an enormous volume of potentially recoverable gas in the eastern United States has a great economic significance. This will be some of the closest natural gas to the high population areas of New Jersey, New York and New England. This transportation advantage will give Marcellus gas a distinct advantage in the marketplace. Gas produced from the shallower, western portion of the Marcellus extent (see map above) might be transported to cities in the central part of the United States. It should have a positive impact on the stability of natural gas supply of the surrounding region for at least several years if the resource estimate quoted above proves accurate.

Gas Leases & Signing Bonuses
Many landowners are being approached with offers to lease their land. The size of the signing bonuses that have been paid in transactions between informed buyers and informed sellers is directly related to two factors: 1) the level of uncertainty in the mind of the buyer, and 2) the number of other buyers competing to make the purchase. These factors have changed significantly in a very short time. As recently as 2005 there was very little interest in leasing properties for Marcellus Shale gas production. The Marcellus was not considered to be an important gas resource and a technology for tapping it had not been demonstrated. At that time the level of uncertainty in the minds of the buyers was very high and the signing bonuses were a few dollars per acre. When the potential of the Marcellus was first suspected in 2006 a small number of speculators began leasing land - paying risky signing bonuses that were sometimes as high as $100 per acre.
In late 2007 signing bonuses of a few hundred dollars per acre were common. Then, as the technology was demonstrated and publicized signing bonuses began to rise rapidly. By early 2008 several wells with strong production rates were drilled, numerous investors began leasing and the signing bonuses rose from a few hundred dollars per acre up to over $2000 per acre for the most desirable properties. If the results of current and future drilling activity do not match the expectations of companies paying for leases the amounts that they are willing to pay could drop rapidly.

Gas Royalties
Although signing bonuses generate an enormous amount of interest because they are guaranteed income, royalties can be significantly higher. A royalty is a share of a well's income. The customary royalty rate is 12.5 percent of the value of gas produced by a well. Higher royalty rates are sometimes paid by aggressive buyers for highly desirable properties. The royalties paid to eligible property owners from a well yielding over one million cubic feet of natural gas per day can be hundreds of thousands of dollars per year. These royalties are divided by all eligible property owners within a production unit (an area of land that is thought to contribute gas to a producing well - typically 640 acres). The amount paid to each eligible property owner is based upon their ownership share. (Get a gas royalty estimate.) If the Marcellus Shale holds up to the optimistic expectations of some natural gas experts, Pennsylvania, Ohio, New York and West Virginia could temporarily have an enormous boost in income that might be sustained for a few decades.

Natural Gas Drilling Activity
Several companies are actively drilling, leasing or planning activity on Marcellus Shale properties. Range Resources, North Coast Energy Inc., Chesapeake Energy, Chief Oil & Gas LLC, East Resources Inc., Fortuna Energy Inc., Equitable Production Company, Cabot Oil & Gas Corporation, Southwestern Energy Production Company, and Atlas Energy Resources are all involved. Shares of most of these companies are up strongly over the past two years. The Pennsylvania Department of Environmental Protection says that drilling permits are up strongly since 2005 and much of the activity increase can be attributed to wells targeting the Marcellus shale. Some of the new wells appear capable of yielding millions of cubic feet per day and that has companies working hard to acquire leases on desirable properties and complete new wells.

Other Gas Shales in the United States
The events described above are not unique to the northeastern United States or the Marcellus Shale. The horizontal drilling and hydrofracing technologies were perfected for shale reservoirs about four years ago in the Barnett Shale of Texas. The technology was then applied to the nearby Fayetteville Shale of northcentral Arkansas. Then, shortly after the Marcellus activity began, drilling and leasing in the Haynesville Shale of northwestern Louisiana started. These are just two of several unconventional gas plays now happening in the United States.